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(dGf) T , P = 0 (1464) Thus if a mixture of chemical species is not in chemical equilibrium, any reaction that occurs at constant T and P must lead to a decrease in the total Gibbs energy of the system The significance of this for a single chemical reaction is seen in Fig 131, which shows a schematic diagram of G' vs E , the reaction coordinate Since E is the single variable that characterizes the progress of the reaction, and therefore the composition of the system, the total Gibbs energy at constant T and P is determined by E The arrows along the curve in Fig 131 indicate the directions of changes in ( G t ) ~ that are possible on account of reaction The reaction coordinate ,p has its equilibrium value E, at the minimum of the curve The meaning of Eq (1464) is that differential displacements of the chemical reaction can occur at the equilibrium state without causing changes in the total Gibbs energy of the system Figure 131 indicates the two distinctive features of the equilibrium state for given temperature and pressure:

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Each of these may serve as a criterion of equilibrium Thus, we may write an expression for G h s a function of E and seek the value of E which minimizes Gt, or we may differentiate the

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As you may have noticed while reading the preceding 11 chapters, not much use has been made of I/O in the example programs In fact, aside from print( ) and println( ), none of the I/O methods have been used significantly The reason is simple: most real applications of Java are not text-based, console programs Rather, they are graphically oriented applets that rely upon Java's Abstract Window Toolkit (AWT) for interaction with the user Although text-based programs are excellent as teaching examples, they do not constitute an important use for Java in the real world Also, Java's support for console I/O is limited and somewhat awkward to use even in simple example programs Text-based console I/O is just not very important to Java programming The preceding paragraph notwithstanding, Java does provide strong, flexible support for I/O as it relates to files and networks Java's I/O system is cohesive and consistent In fact, once you understand its fundamentals, the rest of the I/O system is easy to master

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Java programs perform I/O through streams A stream is an abstraction that either produces or consumes information A stream is linked to a physical device by the Java I/O system All streams behave in the same manner, even if the actual physical devices to which they are linked differ Thus, the same I/O classes and methods can be applied to any type of device This means that an input stream can abstract many different kinds of input: from a disk file, a keyboard, or a network socket Likewise, an output stream may refer to the console, a disk file, or a network connection Streams are a clean way to deal with input/output without having every part of your code understand the difference between a keyboard and a network, for example Java implements streams within class hierarchies defined in the javaio package Note If you are familiar with C/C++, then you are already familiar with the concept of the stream Java's approach to streams is loosely the same as C/C++

expression, equate it to zero, and solve for E The latter procedure is almost always used for single reactions (Fig 13 I), and leads to the method of equilibrium constants, as described in the following sections It may also be extended to multiple reactions, but in this case the direct minimization of G' is often more convenient, and is considered in Sec 139 Although the equilibrium expressions are developed for closed systems at constant T and P , they are not restricted in application to systems that are actually closed and reach equilibrium states along paths of constant T and P Once an equilibrium state is reached, no further changes occur, and the system continues to exist in this state at fixed T and P How this state was actually attained does not matter Once it is known that an equilibrium state exists at given T and P , the criteria apply

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