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In general, these hindrances for odd A nuclei may be divided into ve classes: 1. If the hindrance factor is between 1 and 4, the transition is called a favored transition. In such decays, the emitted a particle is assembled from two low-lying pairs of nucleons in the parent nucleus, leaving the odd nucleon in its initial orbital. To form an a particle within a nucleus, two protons and two neutrons must come together with their spins coupled to zero and with zero orbital angular momentum relative to the center of mass of the a particle. These four nucleons are likely to come from the highest occupied levels of the nucleus. In odd A nuclei, because of the odd particle and the dif culty of getting a partner for it, one pair of nucleons is drawn from a lower lying level, causing the daughter nucleus to be formed in an excited state. 2. A hindrance factor of 4 10 indicates a mixing or favorable overlap between the initial and nal nuclear states involved in the transition. 3. Factors of 10 100 indicate that spin projections of the initial and nal states are parallel, but the wave function overlap is not favorable. 4. Factors of 100 1000 indicate transitions with a change in parity but with projections of initial and nal states being parallel. 5. Hindrance factors of .1000 indicate that the transition involves a parity change and a spin ip, that is, the spin projections of the initial and nal states are antiparallel, which requires substantial reorganization of the nucleon in the parent when the a is emitted.

FIGURE 11.13. Nano-ESI mass spectrum of lipid vesicles composed of 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) reconstituted with model transmembrane peptides acetyl-(GA)3 WW(LA)5 WW(AG)3 -ethanolamine [WALP16(+10)] at a 1:25 ratio [WALP16(+10) : DMPC]. Abundance of the largest aggregate of DMPC detected in this experiment (16-mer, not shown in the spectrum) was four orders of magnitude below that of the DMPC monomer. The peaks labeled as WALP16 are singly charged Na+ adducts of the peptide (the unlabeled low-abundance isotopic cluster shown in the insets corresponds to a protonated form of the peptide). Approximately 200 nL of a vesicle suspension (equivalent of 20 M peptide concentration) was used to acquire the spectrum. Adapted with permission from (106). 2000 National Academy of Sciences, USA.

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The External Event Counter mode operates similarly to the PWM mode however the tlmer 1 5not clocked by the m ~ t r ~ c t ~ n Clock but by lrans111ons01 the T I input signal The edge 8 s selectable t h r o q h the T I C 1 bit 01 the TlCNTRL regster A bloch diagram 01 the timers External Event Counter mode 01 opelation is Shown 8 Figure 16 n The T I input Should be connected to an external device that generates a posil~velnegativegoing pulse tor each event By clocking the timer through T1 the number 01 pos81~velnegative tlan5111on5 can be Counted therefore allowing Sonware to capture the number 01 events that occur The input signal on T I must have a pulse width equal to or greater than one ~nslruclion Clock cycle The counter can be contigured to sense either positive-going or negative-going tranait~onson the T I pin The maximum trequency at whlch lrans111ons can be Sensed IS one-halt the Ire4 ~ e n c y the ~nstruction 01 cloch A5 with the PWM mode. when the counter underflows the

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