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interaction is more positive for the base in the middle of the molecule The base at the end of the molecule, with the smaller positive H, is that much closer to having a negative G and spontaneously unwinding The second component of the Gibbs energy, entropy, also makes it more likely that, for a homogenous DNA, the end of the molecule will unwind first We just saw that the entropy change for a single base going from its helical state to its coil state is positive, since there are more ways to achieve the coil state A positive entropy makes a favorable contribution to the Gibbs energy change ( G 5 H 2 T S) But a single, coil state base in the middle of the molecule is not as free to move as a single, coil state base at the end of the molecule In the middle of the molecule, our lone, coil state base is surrounded on both sides by bases that are still constrained in their helical state This limits the movements of both the sugar phosphate backbone and of the coil base itself A single, coil state base at the end of the molecule has more ways that it can move and still be in the random-coil conformation for that base In both cases S is positive But for the base at the end of the molecule S is larger Both the larger S and the smaller H for the end base make G more negative for the base at the end of the molecule than it is for the base in the middle of the molecule Figure 10-11 compares unwinding

Note: Your MonthCalendar control will circle the current date, which is likely not the date shown in the graphic.

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You will note that the Dock property for our month calendar object is set to Fill. This ensures that the number of months displayed will expand to fill the entire tab page as the form is enlarged. As we will see in the next section, months before the MinDate property value and after the MaxDate value will not be accessible from this control. 11.4.2 INITIALIZING A CALENDAR Now that our MonthCalendar control is on the form, we can hook it up to our PhotoAlbum class. We do not want to initialize the calendar needlessly, so we will only do so when the Dates tab is displayed. By the same token, we do not want to initialize the lstPhotos list box needlessly, so we need to ensure that this only occurs when the Photos tab is displayed. Since we used the method UpdateList for our list box, we will create an UpdateCalendar method to initialize and update our MonthCalendar control. The following steps are required for this change:

INITIALIZE THE MONTH CALENDAR CONTROL Action 1 In the MainForm.cs source file, add an UpdateCalendar method to update the MonthCalendar control in the Dates tab. In this method, calculate the range of dates used by photographs in this album. For each Photograph in the album, record its date and adjust the minimum and maximum date as required. Note: We could use a foreach loop here, of course. A for loop works a little better since an index for the dates array is required.

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DateTime minDate = DateTime.MaxValue; DateTime maxDate = DateTime.MinValue; DateTime[] dates = new DateTime[_album.Count]; for (int i = 0; i < _album.Count; i++) { DateTime newDate = _album[i].DateTaken; dates[i] = newDate; if (newDate < minDate) minDate = newDate; if (newDate > maxDate) maxDate = newDate; if (_album.Count > 0) { monthCalDates.BoldedDates = dates; monthCalDates.MinDate = minDate; monthCalDates.MaxDate = maxDate; monthCalDates.SelectionStart = minDate; } }

Assign the MonthCalendar properties based on the calculated date values. Note: The SelectionStart property ensures that the initial date for the album is displayed by the calendar.

Use the SelectedTab property of the tcPhotos control. 6 Modify the OpenAlbum method to update the appropriate tab page.

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