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Examples are azides (R N3 ), diazoalkanes (R2 C N N), and nitriloxides (R C N O) These have also been labeled as ``propargyl/allenyl anion type'' [270] 2 Eighteen-Electron Those in which the dipolar canonical form has a single bond on the sextet atom and the other forms a double bond Examples are ketocarbenes [R C: C(O)R], azoxy compounds [R N N(O)R], and nitrones [R2 C N(O)R] These have also been labeled as ``allyl anion type'' [270] If all three atoms of the triad belong to the rst row, a total of 18 di erent uncharged species, 6 of the 16-electron kind and 12 of the 18-electron kind, are possible The reactivity and regioselectivity of 1,3-dipolar cycloadditions have been discussed in terms of the frontier orbitals [271] Most of the features may be understood on the basis of simple Huckel MO theory.
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408 409 411 417
The HOMO and LUMO p orbitals and p orbital energies for all 18 combinations of the parent dipoles are shown in Figure 128 The frontier orbitals of many of the 1,3-dipoles have previously been derived by CNDO/2 and extended Huckel theory [272] The rst six structures, all of 16-electron type, are shown in greater detail:.
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x direction to facilitate comparison with the familiar results. For this case, the displacement radius vector is r 0:3 and the displacement angle is y p rad. The last two rows show the results for the general vectorial displacements of r 0:632 and the displacement angle y 0:322 rad (the third row), and r 0:361 and the displacement angle y 5:695 rad (the fourth row). The center of the sheared wavefront is translated by the magnitude of the displacement radius vector r along the direction y with respect to the origin at the center of the square pupil. We discuss each gure in more detail. Figure 4.54 shows the simulated interferometric patterns when 4 waves of defocus and no defocus are added to 2.5 waves of spherical aberration. The second row presenting the intensity patterns of lateral shearing interferometer is in agreement with the patterns presented at the beginning of this chapter. It con rms the general reliability of our simulations. The fringe patterns outside focus appear as
For a string in an expression, Python evaluates any nonempty string to true, and an empty string to false:
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Figure 7.13 The probability distributions of one and ten samples of noise [After: Meikle, H.D., Another way of representing echo signals, their spectra, and their statistics, Proceedings of the German Radar Symposium GRS 2002, Bonn, Germany: DGON, 5th to 9th of September 2002, pp. 509 513.]
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different for each one of two orthogonal lateral shears. Then, if the defocusing is referred to the point in the middle between the compensators, the expression for the fringe pattern becomes @W d @W d x S y T nl: 4:36 @x 2R2 @y 2R2 In this case, the fringes for spherical aberration become S-shaped, similar to those displayed in Figure 4.7. A polarization phase shifter incorporating a birefringent plane parallel plate may be used to measure an aspherical surface. Weijers et al. (1998) present a simple calculation for ray propagation through uniaxial, birefringent element. Its inherent aberrations are derived. The method is used to record directly phase-shifted interferograms as needed for the interferogram evaluation and phase reconstruction. Begbie et al. (2001) performed a rigorous analysis using Mueller matrices to evaluate the state of polarization necessary to eliminate fringe ambiguity.
The expressions (3.351, (3.47), and (3.73) for the Fisher score vector of normal, Poisson, and multinomial observations have the form
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