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One solvent extraction technique involves membrane solvent extraction Ion-exchange resins have been shown to be effective in the puri cation of aqueous caprolactam solutions In one such process, the oily impurities are removed by extraction with organic solvents, followed after treatment with carbon at 60 80 C Cationic and anionic exchange resins are then used to complete the puri cation process Ion-exchange resins remove all ionic impurities as well as colloidal and oating particles, that is, alkali metal salts formed in permanganate treatment are removed during ion-exchange treatment Also the treatment of aqueous solutions of caprolactam with ion-exchange resins helps to remove the distillation residue Treatment of caprolactam with activated carbon helps to remove anionic and cationic impurities Impurities in caprolactam have also been destroyed by oxidation with ozone followed by distillation Ozonation treatment of waste caprolactam leaves no ionic impurities.
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1416 IMPLEMENTATION AND APPLICATIONS In this section, we discuss a number of practical considerations for PSI and also examine some particular applications of PSI A generic PSI system consists of four things: an interferometer, a device for changing the reference phase, a detector or detector array, and a computer The detector array provides the interface between the wavefront and the computer, and the computer provides control of the interferometer and phase shifter and performs the necessary computations The advances in detectors and computers have been the enabling technologies that have driven the dramatic performance improvements and acceptance of PSI There is suf cient computing power in personal computers to handle most PSI applications 14161 Commercial Instrumentation Commercial instrumentation utilizing PSI technology is available for measuring surface and wavefront shape, surface pro le, and distance.
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PSI-based surface pro ling microscopes are widely used for quantitative examination of small surface features and microroughness of both optical and non-optical components Repeatabilities of a few Angstroms RMS can be obtained, and these pro ling instruments are fully discussed in 17 PSI interferometers have been marketed for measuring surfaces and wavefronts based on all three of the optical con gurations shown in Figure 142; Twyman Green, Mach Zehnder and laser Fizeau ( 1 and 2) All of these systems employ video cameras to record the interferograms; the phase shifts are provided by moving the reference objective with PZT transducers, and a variety of reference objectives and ats are available to match the part under test (Smythe et al, 1987; Creath, 1987b) A prominent feature of these systems is the exibility of the user interface provided by the computer As discussed in Section 14.
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and must be equated to the de-embedded measured data. By analytically solving for the intrinsic elements, Im(Y11 + Y12 ) Cgs = Im(Y12 ) Cgd = Im(Y12 + Y22 ) Cin = Cin Re(Y11 ) Cgs Re(Y12 ) 1 Rgd 2 = 2 Cin Cgd Cgs Cgd (Cgd + Cin ) gm = (Re(Y21 Y12 ))2 + (Im(Y21 Y12 ))2 a tanh Re(Y21 Y12 ) Im(Y21 Y12 ) = 2 Re(Y11 ) Rgd 2 Cgd Ri = 2 2 Cgs Rds = 1 Re(Y22 ) (3.73)
However, the most commonly used oxidizing agents are potassium permanganate, perboric acid, perborate, and potassium bromate Treatment of caprolactam with these oxidizing agents is carried out in a neutral medium at 40 60 C Strongly alkaline or acidic conditions accelerate the oxidation of caprolactam to form isocyanates The undesirable oxidation reaction is fast above pH 7 because of the reaction with isocyanate to form carbamic acid salts, which shifts the equilibrium to form additional isocyanate..
15, a large number of graphics displays can be produced, and the processing can be customized to meet the needs of the user A Mach Zehnder interferometer con guration that is available for testing the quality of optical wavefronts with PSI is shown in Figure 1452 (Hayes and Lange, 1983; Creath, 1987b) The output of a source, such as a laser diode, is collimated as it enters the system A spherical reference wavefront is provided by the spatial lter in the reference arm A similar set of optics, without the pinhole, is used in the test arm to match the optical path length in the two arms The beams are recombined and.
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